Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ2N,O}nickel(II)
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منابع مشابه
Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI)
Crystals of the title compound, [Mo(C(14)H(13)NO(2))O(2)(CH(4)O)], were obtained by recrystallization from methanol. The Mo(VI) atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidoprop-yl)iminometh-yl]-2-naphtholate Schiff base ligand. The coordination sphere is completed by the O atom of a methanol mol-ecule, yielding a distorted octa-hedron....
متن کاملcis-Bis{1-[(4-nitrophenyl)diazenyl]-2-naphtholato}dipyridinenickel(II)1
In the title compound, [Ni(C(16)H(10)N(3)O(3))(2)(C(5)H(5)N)(2)], the Ni(II) cation is in a distorted octa-hedral NiN(4)O(2) coordination by two independent bidentate 1-[(4-nitro-phen-yl)diazen-yl]-2-naph-thol-ate anions and two pyridine ligands. C-H⋯O inter-actions between aromatic rings and the O atoms of the nitro substituents build up a two-dimensional supra-molecular arrangement parallel t...
متن کاملDichlorido[1-(8-quinolyliminomethyl)-2-naphtholato]iron(III)
The Fe(III) ion in the title complex, [FeCl(2)(C(20)H(13)N(2)O)], has a distorted square-pyramidal coordination formed by one O atom and two N atoms from a tridentate 1-(8-quinolylimino-meth-yl)-2-naphtholate ligand and two Cl atoms. In the crystal structure, mol-ecules form a column structure along the a axis through π-π stacking inter-actions, with centroid-centroid distances of 3.657 (1) and...
متن کاملAquaazido{3,3′-[o-phenylenebis(nitrilomethylidyne)]di-2-naphtholato}manganese(III)
In the title complex, [Mn(C(28)H(18)N(2)O(2))(N(3))(H(2)O)], the Mn(III) ion adopts a distorted fac-MnO(3)N(3) octa-hedral geometry arising from the O,N,N',O'-tetra-dentate Schiff base ligand, an azide ion and a water mol-ecule. In the crystal, inter-molecular O-H⋯(O,O) and O-H⋯N hydrogen bonds and π-π inter-actions [centroid-centroid separation = 3.5535 (13) Å] link the mol-ecules into chains.
متن کاملBis[1-(2-naphthyliminomethyl)-2-naphtholato-κ2 N,O]copper(II)
In the title complex, [Cu(C(21)H(14)NO)(2)], the Cu(II) atom, lying on an inversion center, is coordinated by two bidentate 1-(2-naphthyl-imino-meth-yl)-2-naphtholate ligands in a trans arrangement, forming a slightly distorted square-planar coordination geometry. The mean planes of two naphthyl systems of the ligand make a dihedral angle of 40.32 (11)°.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811010087